Tetrahedron letters

The 1, 4 O→ C silyl migrations of various 3-[(trialkylsilyl) oxymethyl]-furans and-thiophenes

EJ Bures, BA Keay

文献索引：Bures, Edward J.; Keay, Brian A. Tetrahedron Letters, 1987 , vol. 28, # 48 p. 5965 - 5968

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被引用次数: 43

摘要

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Numerous 3-[(trialkylsilyl)oxymethyl]-furans and -thiophenes undergo a 1,4 O→C silyl migration when treated with n-BuLi/HMPA in THF or DME to produce 2-(trialkylsilyl)-3-(hydroxymethyl)- furans and -thiophenes in good yields. ... Numerous 3-[(trialkylsilyl)oxymethyl]-furans ...