Formation of dicarbonyl compounds in the flash vacuum pyrolysis of saturated bicyclic peroxides

AJ Broodworth, DS Baker, HJ Eggelte

文献索引：Bloodworth, A. J.; Baker, David S.; Eggelte, Henny J. Journal of the Chemical Society, Chemical Communications, 1982 , # 18 p. 1034 - 1036

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摘要

Under flash vacuum pyrolysis, dioxabicyclo [. 2.1] alkanes (= 3, 4, and 5) isomerise to keto- aldehydes, MeCO [CH] CHO, whereas dioxabicyclo [. 2.2] alkanes (= 2, 3, and 4) fragment ot give, by loss of hydrogen and ethylene, mixtures of cycloalkane-1, 4-diones and dialdehydes, OHC [CH] CHO.