Tetrahedron Letters

Alder-ene reaction of aryne with olefins

Z Chen, J Liang, J Yin, GA Yu, SH Liu

文献索引：Chen, Zhao; Liang, Jinhua; Yin, Jun; Yu, Guang-Ao; Liu, Sheng Hua Tetrahedron Letters, 2013 , vol. 54, # 43 p. 5785 - 5787

全文：HTML全文

被引用次数: 7

摘要

Abstract A novel intermolecular Alder-ene reaction based on aryne and olefins was developed. We performed this transformation under mild conditions such as at room temperature, and this reaction displayed high selectivity and good yields only in the presence of CsF. Hence, the intermolecular Alder-ene reaction of aryne with olefins provides an effective route to synthesize derivatives of olefins.