Fourier transform infrared studies of the self-reaction of C2H5O2 radicals

H Niki, PD Maker, CM Savage…

文献索引：Niki, H.; Maker, P. D.; Savage, C. M.; Breitenbach, L. P. Journal of Physical Chemistry, 1982 , vol. 86, p. 3825 - 3829

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被引用次数: 62

摘要

Product studies were made with the FT IR method in the photooxidation of C2H5N2C2H5 and in the C1-atom-initiated oxidation of CzH6 in Oz-Nz mixtures at 700 torr and 298 K. The major products were CH, CHO, C2H50H, and CZH6O2H in both systems. A weak, broad band centered at 1040 cm-'was assigned tentatively to CzH602CzHb The results are consistent with the occurrence of three channels for the self-reaction of C2H5O2 radicals, ...