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Amphiphilic polymer supports for the asymmetric hydrogenation of amino acid precursors in water

…, O Nuyken, R Weberskirch

文献索引:Zarka, M. Tobias; Nuyken, Oskar; Weberskirch, Ralf Chemistry - A European Journal, 2003 , vol. 9, # 14 p. 3228 - 3234

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被引用次数: 106

摘要

Abstract This paper describes the synthesis and characterization of a new class of amphiphilic, water-soluble diblock copolymers based on 2oxazoline derivatives with pendent (2S, 4S)-4-diphenylphosphino-2-(diphenylphosphinomethyl) pyrrolidine (PPM) units in the hydrophobic block. The synthetic strategy involves the preparation of a diblock copolymer precursor with ester functionalities in the side chain; which were converted into ...