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Condensation of diethyl malonate with methyl vinyl ketone

TA Spencer, MD Newton…

文献索引:Spencer,T.A. et al. Journal of Organic Chemistry, 1964 , vol. 29, p. 787 - 789

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被引用次数: 18

摘要

(9) 0. W-ichterle, Chem. Zenlr., 348 (1944).(10) In all cases of Cyclization to cyclohexane-1, 3-diones which we have Investigated (see, e. 0. ref. 2), no reasonable yield of desired product could be obtained unless conditions for enolate precipitation were found. Otherwise, reverse Michael reactions. other condensations, etc., occurred, as in the formation of VI and XI. report that 1-methyl-2-acetylcyclohexene-1 has X, 249 mp (6 6890).