On the neophyl-like rearrangement of 2-(9-anthryl) ethyl radicals

R Leardini, D Nanni, GF Pedulli, A Tundo…

文献索引：Leardini, Rino; Nanni, Daniele; Pedulli, Gian Franco; Tundo, Antonio; Zanardi, Giuseppe; et al. Journal of the American Chemical Society, 1989 , vol. 111, # 20 p. 7723 - 7732

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被引用次数: 23

摘要

Abstract: The 1, 2 migration of the aryl group in deuterated 2-(9-anthryl) ethyl and 2-[9-(10- phenylanthryl)] ethyl radicals has been studied by product analyses with the use of the competing reaction ArCH2CD2'+ Bu3SnH. The rearrangement was so fast that equimolecular mixtures of the unrearranged (ArCH2CD2H) and rearranged (ArCD2CH3) hydrocarbons were obtained even in the presence of a large excess of Bu3SnH (ca. 1 M). ...