Zirconocene-. eta. 4-1, 3-pentadiene complex and its higher homologs. A new synthetic method involving. sigma.-. pi. rearrangement of the hydrido-2, 4- …

H Yasuda, K Nagasuna, M Akita, K Lee…

文献索引：Yasuda, H.; Nagasuna, K.; Akita, M.; Lee, K.; Nakamura, A. Organometallics, 1984 , vol. 3, p. 1470 - 1478

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被引用次数: 66

摘要

The (1, 3-entadiene) zirconocene complex and ita higher homologues of the type (q5-C5H5) 2Zr (CR'-substituted pentadienyl anions through novel mrearrangement of hydrido-2, 4- pentadienylzirconium species. The'H NMR studies on these complexes revealed that the 1, 3-pentadiene and 2, 4-hexadiene complexes are composed of ca. 1: l mixture of s-cis and s- trans isomers while each of the complexes containing 2-methyl-l, 3-pentadiene, 3-methyl-l ...