Journal of organometallic chemistry

Synthesis of ketoalkyltin chlorides via in-situ condensation and hydrostannation of ketonic substrates

JW Burley, P Hope, AG Mack

文献索引：Burley, Joseph W.; Hope, Peter; Mack, Arthur G. Journal of Organometallic Chemistry, 1984 , vol. 277, # 1 p. 37 - 46

全文：HTML全文

被引用次数: 2

摘要

Abstract Reactions between hydrogen chloride, stannous chloride and aliphatic ketones yield 3-ketoalkyltin trichlorides via the in-situ generation of α, β-unsaturated ketones. The analogous reactions between hydrogen chloride, tin and aliphatic ketones give rise to mixtures of 3-ketoalkyltin trichlorides and the corresponding bis (3-ketoalkyl) tin dichlorides. β-Hydroxyketones, which are intermediates in the acid-catalysed synthesis of α, β- ...