The Journal of organic chemistry

Electrochemical Synthesis of 1, 2-Disilylethanes from α-Silylacetic Acids

AV Shtelman, JY Becker

文献索引：Shtelman, Alex V.; Becker, James Y. Journal of Organic Chemistry, 2011 , vol. 76, # 11 p. 4710 - 4714

全文：HTML全文

被引用次数: 12

摘要

The synthesis of 1, 2-disilylethanes [R1R2R3Si (CH2) 2SiR1R2R3] is usually conducted by using noble metal reagents or catalysts. This work describes a new electrochemical synthetic method for their preparation in good yields by oxidation of α-silylacetic acids at Pt anodes (Kolbe electrolysis). Most of the reported synthesized 1, 2-disilylethanes in this work are unknown.