Organosilicon compounds. XCVI. Intramolecular hydrogen bonds in phenylsilylalkanols

J Pola, Z Papoušková…

文献索引：Pola,J. et al. Collection of Czechoslovak Chemical Communications, 1973 , vol. 38, p. 1522 - 1527

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被引用次数: 10

摘要

Intramolecular hydrogen bonds in compounds of the type C6Hs (CH3hSi (CHz) nOH (1/= 1, 2) and in (C6HshSiCH20H were studied by IR spectroscopy. By comparison with intramolecular hydrogen bonds in the carbon analogues, ro-phenylalkanols, the silicon atom weakens this interaction. Possible reasons for this phenomenon are discussed. IR spectroscopy was also used to determine acidities of the phenylsilylalkanols and ...