Synlett

A practical removal method of camphorsultam

T Hasegawa, H Yamamoto

文献索引：Hasegawa, Tomoyuki; Yamamoto, Hisashi Synlett, 1998 , # 8 p. 882 - 884

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被引用次数: 17

摘要

Oppolzer's sultam has been shown to be a versatile chiral auxiliary in various diastereoselective carbon-carbon bond constructions.1-7 Effective methods for removal of this chiral auxiliary8,9 have been reported, for example, lithium hydrogen peroxide was utilized to convert N-acyl sultam directly into the corresponding carboxylic acids without racemization of the newly created stereocenters.10 This method, however, requires a large volume of solvent and long ...