Anion effects on construction of Zn II compounds with a chelating ligand bis (2-pyridylmethyl) amine and their catalytic activities

…, GH Eom, SH Kim, HM Park, YS Choi, HG Jang…

文献索引：Kim, Youngmee; Park, Byeong Kwon; Eom, Geun Hee; Kim, Soo Hyun; Park, Hyun Min; Choi, Young S.; Jang, Ho G.; Kim, Cheal Inorganica Chimica Acta, 2011 , vol. 366, # 1 p. 337 - 343

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被引用次数: 12

摘要

Three ZnII complexes containing bispicam ligands (bispicam= bis (2-pyridylmethyl) amine),[Zn (bispicam) 2](NO3) 2· 2CH3OH 4A,[Zn (bispicam)(NO3) 2] 4B, and [Zn (bispicam) 2](OTf) 26, were obtained, and their structures were determined by X-ray crystallography. Complexes of the general formulation [Zn (bispicam) 2] X2 (X= Cl−(1), Br−(2), I−(3), NO3−(4A), ClO4−(5), and OTf−(6)) show fac geometric isomers (a) or enantiomers (c) and ...