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A highly versatile synthesis of 2, 2-dimethyl-3-(2, 2-dichlorovinyl) cyclopropane-1-carboxylic acid esters

HS Bevinakatti, RV Newadkar, DP Borude…

文献索引:Bevinakatti, H. S.; Newadkar, R. V.; Borude, D. P.; Mandal, A. K. Journal of Organic Chemistry, 1988 ,  vol. 53,  # 16  p. 3843 - 3845

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被引用次数: 7

摘要

After cooling, the solution was continuously extracted with ether for 18 h. The ether was removed at reduced pressure, leaving a yellow oil, which crystallized on standing and proved to be the title acid (111 g, 97%), which was characterized by conversion to its ethyl ester, whc se physical properties were in accord with literature data: 15'H NMR (CC14) 6 4.17 (2 H, q, J= 7 Hz), 3.27 (5 H, m), 1.27 (3 H, t, J= 7 Hz); 13C NMR (CC14) 201.48 (C3),