The Journal of Organic Chemistry

8a, 9-Dihydro-8a-methyl-9-methyleneanthracene: a hydrocarbon with fused blocked aromatic rings

B Miller, J Baghdadchi

文献索引：Miller, Bernard; Baghdadchi, Jamil Journal of Organic Chemistry, 1987 ,  vol. 52,  # 12  p. 2391 - 2396

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被引用次数: 2

摘要

The title compound 1 was prepared from diketone 2 by a four-step synthesis. Photorearrangement of 1 proceeded slowly compared to that of the corresponding fused blocked aromatic ketone A to form 1, lO-dimethylanthracene in variable yields. Thermolysis of 1 yielded the “double aromatization” product, 9-ethylanthracene. The thermal rearrangement was not affected by the addition of free radical chain inhibitors. An attempt ...