Reactions of 1, 3-Dienes with Acrylates by Means of Transition Metal Complex Catalysts

A Misono, Y Uchida, T Saito, K Uchida

文献索引：Misono,A. et al. Bulletin of the Chemical Society of Japan, 1967 , vol. 40, p. 1889 - 1893

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被引用次数: 17

摘要

The reactions of 1, 3-dienes with acrylates by the use of catalyst systems composed of transition-metal acetylacetonates and triethylaluminum were studied. Butadiene and isoprene react with acrylates to give hepta-2, 5-dienoates and 5-or 6-methylhepta-2, 5- dienoates respectively, by means of the binary catalyst system consisting of cobalt (III) or iron (III) acetylacetonate and triethylaluminum. The effects on this reaction of changing the ...