Exploratory studies of H-atom abstraction and silyl-transfer photoreactions of silylalkyl ketones and (silylalkyl) phthalimides

YJ Lee, R Ling, PS Mariano, UC Yoon…

文献索引：Lee, Yean Jang; Ling, Rong; Mariano, Patrick S.; Yoon, Ung Chan; Kim, Dong Uk; Oh, Sun Wha Journal of Organic Chemistry, 1996 , vol. 61, # 10 p. 3304 - 3314

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被引用次数: 19

摘要

Exploratory studies have been conducted to probe competitive H-atom abstraction and SET- promoted, silyl-transfer reactions of excited states of silylalkyl ketones and (silylalkyl) phthalimides. Photochemical investigations with the (silylalkyl) phthalimides have demonstrated that typical γ-H atom abstraction reactions occur upon irradiation in less polar and less silophilic solvents. In contrast, irradiation of these substances in polar-protic- ...