Tetrahedron

Attempts at vinyl radical carbonylation through cyclization onto carbonyl and cyano groups

PC Montevecchi, ML Navacchia, P Spagnolo

文献索引：Montevecchi, Pier Carlo; Navacchia, Maria Luisa; Spagnolo, Piero Tetrahedron, 1998 , vol. 54, # 28 p. 8207 - 8216

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被引用次数: 18

摘要

Sulfanylvinyl radicals 4–6, 16, produced from toluenesulfanyl radical addition to alkynes 1– 3, 15, gave only products arising from cyclization onto the thiophenyl ring and H-abstraction. No products were obtained deriving from possible 5-membered cyclization onto the esteric or thioesteric carbonyl group. Similar results were obtained from toluenesulfanyl radical addition to alkynyl nitriles 20 and 24, which did not provided any evidence for 5-or 6- ...