Tetrahedron

Copper MOF: scope and limitation in catalytic hydroxylation and nitration of aryl halides

S Priyadarshini, PJA Joseph, ML Kantam, B Sreedhar

文献索引：Priyadarshini; Amal Joseph; Kantam, M. Lakshmi; Sreedhar Tetrahedron, 2013 , vol. 69, # 31 p. 6409 - 6414

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被引用次数: 8

摘要

The potential catalytic application of MOFs like [Cu3 (btc) 2](btc= 1, 3, 5- benzenetricarboxylate),[Cu (bdc)](bdc= 1, 4-benzenedicarboxylate),[Cu (pymo) 2](pymo= 2- hydroxypyrimidinalote) and [Cu (im) 2](im= imidazolate) was explored in the hydroxylation and nitration of aryl halides. Cu3 (btc) 2 was found to be superior for both the reactions furnishing good to excellent yields of the respective products. The studies demonstrated ...