Carbon magnetic resonance of organometallic Compounds: Hyperconjugative effects in benzylsilanes

SQA Rizvi, BD Gupta, W Adcock, D Doddrell…

文献索引：Rizvi,S.Q.A. et al. Journal of Organometallic Chemistry, 1973 , vol. 63, p. 67 - 77

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被引用次数: 18

摘要

A number of benzylsilanes have been synthesised and characterised, and the structural features of certain of these compounds are such that the C Si bond is constrained to varying degrees to the nodal plane of the aromatic system. The proton-decoupled, natural-abundance 13 C NMR spectra of these compounds have been obtained and essentially completely assigned on the basis of signal intensities, chemical shifts, selective deuteration and (in some cases) the ...