The role of the metal connectors AgNO 3, Cu 2 I 2 and CuCl 2 in co-ordination-polymer formation using the N 2 S 2 ditopic ligand 1, 4-bis (2- …

LR Hanton, K Lee

文献索引：Hanton, Lyall R.; Lee, Kitty Journal of the Chemical Society, Dalton Transactions, 2000 , # 7 p. 1161 - 1166

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被引用次数: 53

摘要

The extended-reach ligand 1, 4-bis (2-pyridylmethylsulfanylmethyl) benzene (L) was prepared by base coupling of 2-(chloromethyl) pyridinehydrochloride and 1, 4-bis (sulfanylmethyl) benzene. This new ligand was treated with metal connectors AgNO3, CuX (X= Cl, Br or I) and CuCl2 to give co-ordination polymers. The crystal structures of [Ag2 (L)(NO3) 2]∞,[Cu2 (L) I2]∞ and [Cu (L) Cl2]∞ were determined. Comparison of the ...