Inorganic chemistry

Titanium (IV) complexes of disulfide-linked schiff bases

A Donzelli, I Metushi, PG Potvin

文献索引：Donzelli, Alberto; Metushi, Imir; Potvin, Pierre G. Inorganic Chemistry, 2012 , vol. 51, # 9 p. 5138 - 5145

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被引用次数: 5

摘要

With the goal of preparing Ti(IV) complexes bearing a sulfur-based redox function of possible use in electrocatalytic oxidations of alcohols at electrode surfaces, a series of seven 2,2′-dithiodianiline Schiff-base derivatives, including two new variations, were tested in reactions with Ti(OR) 4 (R = i Pr, t Bu). Instead of the expected dimetallic products of general formula [LTi(OR) 2 ] 2 , mononuclear species LTi(OR) 2 were obtained, confirmed by crystallographic ...