Oxidative cleavage of cyclopropanes. IV. Kinetics of the cleavage of arylcyclopropanes by mercuric acetate

RJ Ouellette, RD Robins, A South Jr

文献索引：Ouellette,R.J. et al. Journal of the American Chemical Society, 1968 , vol. 90, p. 1619 - 1624

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被引用次数: 25

摘要

Abstract: The kinetics of cleavage of six arylcyclopropanes by mercuric acetate in acetic acid have been examined. The reaction is over-all second order, first order in each reactant. Activation parameters have been determined from the rates of the reactions at 25, 50, and 75”. Electron-releasing substituents facilitate the reaction. A correlation of the second-order rate constants and cr-has been obtained for the substituents p-MeO, p-Me, rn-Me, H, p-C1, ...