Proximity Effects. XLIII. The Solvolysis of 4-Cyclooctene-1-methyl Brosylate1, 2

AC Cope, DL Nealy, P Scheiner…

文献索引：Cope,A.C. et al. Journal of the American Chemical Society, 1965 , vol. 87, # 14 p. 3130 - 3135

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被引用次数: 35

摘要

of bicyclic products from the solvolyses of cycloalkenylalkyl arenesulfonates have been The extension of these studies to a homolog of 1, 4-cyclooctene-lmethyl brosylate (S), is reported in this paper. Two points of interest arise in comparison of the solvolyses of 1 and 5. First, 1 gives rise to a symmetrical ion 4, while the analogous bridged ion from 5 is unsymmetrical and could lead to derivatives of either bicyclo [3.3. 1]-nonane or bicyclo [4.2. llnonane. ...