Metal–organic frameworks exhibiting strong anion–π interactions

…, H Krautscheid, KV Domasevitch

文献索引：Gural'skiy, Il'ya A.; Solntsev, Pavlo V.; Krautscheid, Harald; Domasevitch, Konstantin V. Chemical Communications, 2006 , # 46 p. 4808 - 4810

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被引用次数: 38

摘要

Coordination polymers offer a significant potential for applications in adsorption, guest and anion recognition and sensing. 1 Their structure commonly provides binding sites for such specific interactions as π–π stacking and XH⋯π hydrogen bonding. 2 The latter reflects the ability of the π-cloud to interact with positively polarized atoms. An electrostatic interaction between anionic species and electron deficient heterocycles, which parallels the above binding scheme, is ...