前往化源商城

1: 2??sequence??regulated radical copolymerization of naturally occurring terpenes with maleimide derivatives in fluorinated alcohol

…, K Satoh, M Kamigaito

文献索引:Matsuda, Masaru; Satoh, Kotaro; Kamigaito, Masami Journal of Polymer Science, Part A: Polymer Chemistry, 2013 , vol. 51, # 8 p. 1774 - 1785

全文:HTML全文

被引用次数: 27

摘要

Abstract Naturally occurring bulky terpenes, such as (+)-and (–)-limonene and (–)-β-pinene, were quantitatively copolymerized with maleimide (MI) derivatives (ie, phenyl-, cyclohexyl-, ethyl-, and unsubstituted-MI) in PhC (CF 3) 2 OH solvent via selective 1: 2-alternating propagation governed by the penultimate effect, which resulted in 1: 2-sequence regulated polymers with relatively high glass transition temperatures and optical activities. Similar ...