Chemistry of dicyclopropylcarbene and related intermediates in dimethyl sulfoxide

PK Freeman, SE Wuerch, GE Clapp

文献索引：Freeman, Peter K.; Wuerch, Stephen E.; Clapp, Gary E. Journal of Organic Chemistry, 1990 , vol. 55, # 9 p. 2587 - 2590

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被引用次数: 4

摘要

Cyclopropyl groups are also quite effective at stabilizing free radical intermediates5 as revealed, for example, in the enhanced rate for decomposition of cyclopropaneacetyl peroxide relative to cyclohexaneacetyl peroxide. 6 Martin and Timberlake measured the rates of decomposition of the dialkyl azo substrates 5-8 and observed a monotonic