Substitution??and Elimination??Free Phosphorylation of Functionalized Alcohols Catalyzed by Oxidomolybdenum Tetrachloride

…, VD Pawar, JQ Kao, CT Chen

文献索引：Liu, Cheng-Yuan; Pawar, Vijay D.; Kao, Jun-Qi; Chen, Chien-Tien Advanced Synthesis and Catalysis, 2010 , vol. 352, # 1 p. 188 - 194

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被引用次数: 13

摘要

Abstract Among 14 oxidometallic species examined for catalytic phosphorylation of the tested alcohols, oxidomolybdenum tetrachloride (MoOCl 4) was found to be the most efficient with a negligible background reaction mediated by triethylamine (Et 3 N). The new catalytic protocol can be applied to the chemoselective phosphorylations of primary, secondary and tertiary alcohols as well as the substitution-free phosphorylations of allylic, ...