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… in basic solutions. Part 26.1 The mechanisms of the base-catalysed cyclisation of 1, 2-diacetylbenzene, 1, 8-diacetylnaphthalene, 4, 5-diacetylphenanthrene and2, 2 …

K Bowden, A Brownhill

文献索引:Bowden, Keith; Brownhill, Andrew Journal of the Chemical Society. Perkin Transactions 2, 1997 , # 5 p. 997 - 1001

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摘要

Rate coefficients have been measured for the base-catalysed cyclisation of 1, 2- diacetylbenzene 1, 1, 8-diacetylnaphthalene 2, 4, 5-diacetylphenanthrene 3 and 2, 2′- diacetylbiphenyl 4 in a range of aqueous dimethyl sulfoxide (DMSO) compositions at 30.0° C, as well as at 45.0 and 60.0° C at certain concentrations, containing tetramethylammonium hydroxide. For three of the substrates, 1, 2 and 4, the di-[2H3] acetyl compounds were also ...