Journal of organometallic chemistry

Catalytic hydrosilylation of acetylenes mediated by phosphine complexes of cobalt (I), rhodium (I), and iridium (I)

LD Field, AJ Ward

文献索引：Field, Leslie D.; Ward, Antony J. Journal of Organometallic Chemistry, 2003 , vol. 681, # 1-2 p. 91 - 97

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被引用次数: 36

摘要

The complexes [Co (PPh3) 3Cl](1),[Co (PPh3) 2 (CO) 2Cl](2),[Co (PMe3) 3Cl](3),[Co (PMe3) 2 (CO) 2Cl](4),[Rh (dppe)(CO) Cl](5),[Rh (PPh2Me) 2 (CO) Cl](6),[Ir (dppe)(CO) Br](7), and [Ir (PPh2Me) 2 (CO) Cl](8) catalyse the hydrosilylation of a range of acetylenes including 1- hexyne, phenylacetylene, and 1-phenyl-1-propyne with triethylsilane. In the case of 1- hexyne and 1-phenyl-1-propyne, only the expected hydrosilylation products were ...