Catalyzed Reactions of Enol Ethers with SN1 Active Groups: A Novel Method for the Preparation of α??Alkylated Ketones

…, C Stock, D Geich??Gimbel

文献索引：Gansaeuer, Andreas; Fielenbach, Doris; Stock, Christoph; Geich-Gimbel, Daniel Advanced Synthesis and Catalysis, 2003 , vol. 345, # 8 p. 1017 - 1030

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被引用次数: 21

摘要

Abstract The performance of tert-alkylations, alkoxyalkylations, and aldehyde enolate allylations proceeding with low catalyst loading (0.1 mol%–5 mol%) is described. The reactions are complete within short times and can even be performed without solvent and under ambient conditions. The mechanism of the reaction was investigated by deuterium labeling and cross-over studies.