Reaction kinetics investigation of 1??fluoro??2, 4??dinitrobenzene with substituted anilines in ethyl acetate–methanol mixtures using linear and nonlinear free energy …
J Jamali??Paghaleh, AR Harifi??Mood…
文献索引：Jamali-Paghaleh, Javad; Harifi-Mood, Ali Reza; Gholami, Mohammad Reza Journal of Physical Organic Chemistry, 2011 , vol. 24, # 11 p. 1095 - 1100
Abstract Aromatic nucleophilic substitution reaction of 1-fluoro-2, 4-dinitrobenzene with para- substituted and meta-substituted anilines was kinetically investigated in the mixtures of ethyl acetate and methanol at room temperature. The correlation of second-order rate coefficients with Hammett's substituent constants yields a fairly linear straight line with negative slope in different mole fractions of ethyl acetate–methanol mixtures. The measured rate coefficients ...
