The preparation of various aliphatic halides and halohydrin compounds

MT Bogert, EM Slocum

文献索引：Bogert; Slocum Journal of the American Chemical Society, 1924 , vol. 46, p. 765

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被引用次数: 7

摘要

For the conversion of trimethylene glycol into the corresponding bromide or iodide, it was ascertained that the phosphorus trihalide could be substituted successfully for the pentahalide. Differences were observed in the behavior of trimethylene glycol with the hydrogen halides. At 0 O, both hydrogen iodide and hydrogen bromide formed solid crystalline addition products with it, which when heated changed nearly quantitatively into ...