Tetrahedron Letters

Facile synthesis of α-iodo carbonyl compounds and α-iodo dimethyl ketals using molecular iodine and trimethylorthoformate

JS Yadav, G Kondaji, MSR Reddy, P Srihari

文献索引：Yadav; Kondaji; Shiva Ram Reddy; Srihari Tetrahedron Letters, 2008 , vol. 49, # 23 p. 3810 - 3813

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被引用次数: 12

摘要

The synthesis of α-halogenated ketones particularly α-iodo ketones and their applications as reaction intermediates have attracted considerable attention in various organic transformations. 1 Several methods are available for the synthesis of α-iodo ketones which are either obtained directly by treating ketones with different combinations of reagents such as iodine–cerium(IV) ammonium nitrate—in alcohol or acetic acid, 2 iodine–mercury(II) ...