2-Imino-3-(o-aminoaryl)-4-thiazolines (II) gave thiazolo-benzotriazepines (I) on condensation with various aliphatic carboxylic acids. Both N-acyl (III) and N, N′-diacyl derivatives (IV) were isolated, and the monoacyl derivatives (III) were also cyclized to thiazolo-benzo-triazepines.