The Journal of Physical Chemistry

Dephosphorylation and aromatic nucleophilic substitution in an alkoxide functionalized micelle

CA Bunton, LH Gan, G Savelli

文献索引：Bunton, Clifford A.; Gan, Leong-Huat; Savelli, Gianfranco Journal of Physical Chemistry, 1983 , vol. 87, # 26 p. 5491 - 5498

全文：HTML全文

被引用次数: 22

摘要

Dephosphorylation of p-nitrophenyl diphenyl phosphate (pNPDPP) and aromatic nucleophilic: substitution on 2, 4-dinitrochlorobenzene and-naphthalene (DNCB and DNCN, respectively) have been examined in aqueous micelles of the functional surfactant hexadecyl (2-hydroxyethyl) dimethylammonium hydroxide, n-C16H33N+- Me2CH2CH20HOH-(2). The variation of the first-order rate constant, lz,, with concentration ...