Catalytic epoxidation activity of Keplerate polyoxomolybdate nanoball toward aqueous suspension of olefins under mild aerobic conditions

A Rezaeifard, R Haddad, M Jafarpour…

文献索引：Rezaeifard, Abdolreza; Haddad, Reza; Jafarpour, Maasoumeh; Hakimi, Mohammad Journal of the American Chemical Society, 2013 , vol. 135, # 27 p. 10036 - 10039

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被引用次数: 51

摘要

Metal-catalyzed aerobic oxidation represents the most elegant and environmentally friendly route for a large-scale production of invaluable oxidation products.(1) The utilization of molecular oxygen for a catalytic oxidation without reducing reagents or radical initiators is a rewarding goal. This is due to the highest content of active oxygen in molecular oxygen and lack of byproducts, contrary to various other oxidants. However, only a few ideal homogeneous epoxidations of ...