Octachloroazulene

…, J Chang, J Jorgensen, DM Lemal

文献索引：Lou, Yan; Chang, Joanne; Jorgensen, Jeffrey; Lemal, David M. Journal of the American Chemical Society, 2002 , vol. 124, # 51 p. 15302 - 15307

全文：HTML全文

被引用次数: 36

摘要

The title compound, the first perhaloazulene, has been synthesized from hexachlorobutadiene and cyclopentadiene. Further chlorination of 1, 3, 4, 5, 6, 7- hexachloroazulene results in addition, not substitution, under electrophilic as well as free radical conditions. Radical chlorination of the hexachloroazulene affords in good yield a single decachlorotetrahydroazulene. Treatment of this Cl10 compound with one equiv of a ...