Tetrahedron

Oxidative degradation of fragrant aldehydes. Autoxidation by molecular oxygen

…, JM Aubry, C Penverne, D Favier, V Nardello-Rataj

文献索引：Marteau; Ruyffelaere; Aubry; Penverne; Favier; Nardello-Rataj Tetrahedron, 2013 , vol. 69, # 10 p. 2268 - 2275

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被引用次数: 16

摘要

The oxidative degradation of fragrant aldehydes by molecular oxygen has been investigated. The oxygen consumption was monitored and the bond dissociation energy (BDE) of the aldehyde C (O)–H bond were calculated by DFT method. The oxidation products were identified by GC/MS. The different pathways accounting for the oxidative degradation are discussed. The main product is the acid, beside the formate ester. Both ...