Pd–NHC Catalyzed Conjugate Addition versus the Mizoroki–Heck Reaction

AL Gottumukkala, JG de Vries…

文献索引：Gottumukkala, Aditya L.; Devries, Johannes G.; Minnaard, Adriaan J. Chemistry - A European Journal, 2011 , vol. 17, # 11 p. 3091 - 3095

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被引用次数: 48

摘要

The transition-metal-catalyzed conjugate addition of aryl organometallic reagents constitutes a cornerstone in organic chemistry.[1] The use of copper has been very successful for the conjugate addition of hard organometallics like Grignard reagents.[2] However, rhodium-[3] and palladiumcatalyzed [4] conjugate additions of soft organometallics are becoming increasingly popular due to their broad functional group tolerance, mild reaction ...