The Synthesis and Decomposition Kinetics of Some para-Substituted trans-γ-Benzylidenebutyryl Peroxides. The Excess α, γ-Bis (biphenylene)-β-phenylallyl Method …

RC Lamb, LP Spadafino, RG Webb…

文献索引：Lamb,R.C. et al. Journal of Organic Chemistry, 1966 , vol. 31, p. 147 - 153

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被引用次数: 14

摘要

Syntheses are described for four trunsd-(pX-phenyl) 4-pentenoyl peroxides and their precursors, in which the substituents X are C1, F, CHa, and OCH,. The decomposition kinetics of these peroxides, as well as the parent peroxide (X= H) were determined in benzene at 50, 60, and 70" by measuring the fading of the stable radical 01, r-bis (bipheny1ene)-P-phenylallyl (BDPA); the free-radical efficiencies of the peroxide ...