Tetrahedron

Acidic ionic liquid [NMP] H 2 PO 4 as dual solvent-catalyst for synthesis of β-alkoxyketones by the oxa-Michael addition reactions

H Guo, X Li, JL Wang, XH Jin, XF Lin

文献索引：Guo, Hui; Li, Xia; Wang, Jun-Liang; Jin, Xiao-Han; Lin, Xian-Fu Tetrahedron, 2010 , vol. 66, # 42 p. 8300 - 8303

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被引用次数: 36

摘要

Acidic ionic liquid N-methyl-2-pyrrolidonium dihydrogen phosphate [NMP] H2PO4 was prepared and used as efficient catalyst and reaction medium to synthesize β-alkoxyketones by the oxa-Michael addition reactions for the first time. The effect of anions and cations, amount of ionic liquid on the reaction was investigated. Various alcohols and phenols proceeded smoothly and led to corresponding β-alkoxyketones with high yields under ...