Journal of the American Chemical Society

The modes of. beta.-silyl involvement in solvolysis

JB Lambert, RB Finzel

文献索引：Lambert, Joseph B.; Finzel, Rodney B. Journal of the American Chemical Society, 1982 , vol. 104, # 7 p. 2020 - 2022

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被引用次数: 50

摘要

Communications to the Editor J. Am. Chem. SOC.. Vol. 104, No. 7, 1982 2021 is a conformational mixture of two forms. The cis molecule has a gauche relationship between silicon and the leaving group in both forms (3 and 3'), so that neither vertical nor nucleophilic participation is possible. 15 The trans molecule exists as an equilibrium between the gauche diequatorial form and the anti diaxial form 4. The latter is not destabilized by the ...