Novel photoreaction using diphenyl disulfide derivatives: Photoinduced oxidation of allyl alcohol

T Tsuboi, Y Takaguchi, S Tsuboi

文献索引：Tsuboi, Takaaki; Takaguchi, Yutaka; Tsuboi, Sadao Bulletin of the Chemical Society of Japan, 2008 , vol. 81, # 3 p. 361 - 368

全文：HTML全文

被引用次数: 8

摘要

Allyl alcohols are oxidized to acrylaldehydes using diphenyl disulfide derivatives upon photoirradiation. The reaction occurs via α-hydrogen abstraction by a sulfanyl radical. Interestingly, the oxidation reaction occurs in moderate yield when a dendrimer disulfide is used as a mediator.