Regiospecific synthesis of trimethylsilyl enol ethers via silatropic rearrangements

RM Coates, LO Sandefur…

文献索引：Coates,R.M. et al. Journal of the American Chemical Society, 1975 , vol. 97, p. 1619 - 1621

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被引用次数: 32

摘要

(CH,), COO*+(CH,), CHCH, X-(CH,), COOH+(CH3), CCH2X (4) and the propagation rate constant that is measured is k,'. Measurements of homopropagation rate constants at 30'for organic substrates with unactivated CH's (eg, isobutane 3) and organic substrates with a- bromo and a-chloro substituents (eg, isopropyl bromide 4 and isopropyl chloride 5) is not possible because kinetic chain lengths are too short." A propagation rate constant of 0.003 ...