Journal of the American Chemical Society

Isomerization of alkylphosphites. III. The synthesis of n-alkylphosphonic acids

GM Kosolapoff

文献索引：Kosolapoff Journal of the American Chemical Society, 1945 , vol. 67, p. 1182

全文：HTML全文

被引用次数: 105

摘要

Summary 1. Dicyclopentadiene reacts with hydrochloric, hydrobromic, hydriodic and thiocyanic acids to yield unsaturated addition-rearrangement products. I t also adds organic carboxylic acids to one of itsdouble bonds to yield esters of hydroxy-dihydro-nor- dicyclopentadiene. These reactions are catalyzed by hydrogen ions or by acidic catalysts. Thioglycolic acid adds to dicyclopentadiene to yield an unsaturated thioether instead of an ...