Photosolvolysis of O, O, S-trimethyl phosphorodithioate. Evidence for an SN 1 (P) mechanism
…, CAG Konings, DHJM Platenburg, R Deen
文献索引：Benschop, Hendrik P.; Konings, Cornelis A. G.; Platenburg, Dominique H. J. M.; Deen, Rudolf Journal of the Chemical Society, Chemical Communications, 1980 , # 9 p. 370 - 372
Irradiation (254 nm) of (MeO) P (S) SMe in ROH yields mainly (66%, R= Pr) the ionic photosolvolysis product (MeO) P (S) OR with the very low capture ratio 1· 9±0· 4 for R= Me R= Pr under competitive photosolvolysis conditions, whereas irradiation in tetrahydrofuran and CHCl gives free-radical products, suggesting th
