Electron-transfer substitution reactions: leaving groups
N Kornblum, P Ackermann, JW Manthey…
文献索引：Kornblum, Nathan; Ackermann, Peter; Manthey, Joseph W.; Musser, Michael T.; Pinnick, Harold W.; et al. Journal of Organic Chemistry, 1988 , vol. 53, # 7 p. 1475 - 1481
A number of groups that do not participate in SN2 displacement processes are able to function as leaving groups in electron-transfer chain reactions at room temperature; such groups include azide, sulfone, ethers, nitro, quaternary ammonium ions, esters, and thioethers. Even carbanions are able to function as leaving groups as can be seen from fragmentation of carbon-carbon bonds.
