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Rational Design of a Palladium??Catalyzed Csp–Csp Cross??Coupling Reaction Inspired by Kinetic Studies

Y Weng, B Cheng, C He, A Lei

文献索引:Weng, Yue; Cheng, Ben; He, Chuan; Lei, Aiwen Angewandte Chemie - International Edition, 2012 , vol. 51, # 38 p. 9547 - 9551

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被引用次数: 35

摘要

Owing to the unique chemical and physical properties of diynes, along with their wide applications in pharmaceuticals and materials chemistry, these compounds have attracted the attention of scientists for decades.[1] However, the synthesis of diynes still remains a great challenge. Compared with the intensively developed synthetic methods for biaryl and arylalkynes (Csp2–Csp2 and Csp2–Csp couplings), the methods for Csp–Csp coupling ...