Chemistry Letters

Novel syntheses of bis (trialkylsilyl) amines by reductive trialkylsilylation of azo compounds

M Kira, S Nagai, M Nishimura, H Sakurai

文献索引：Kira, Mitsuo; Nagai, Satoshi; Nishimura, Mitsushi; Sakurai, Hideki Chemistry Letters, 1987 , p. 153 - 156

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被引用次数: 5

摘要

Reduction of azo compounds with a system of a trialkylchlorosilane and lithium has been found to afford bis (trialkylsilyl) amines in the presence of a transition metal halide as a catalyst in THF. The reaction course was significantly modified by using t- butyldimethylchlorosilane as a trialkylchlorosilane.